Journal of Fluorine Chemistry p. 35 - 40 (1995)
Update date:2022-08-10
Topics:
Lanier Marion
Pastor, Raphaeel
The stereoselective preparation of 3-F-alkyl 2-propenoates and their derivatives is described.E-isomers are easily obtained by an in situ reduction-olefination from esters of F-acids and phosphonates or by a convenient dehydration of 3-F-alkyl 3-hydroxyesters.Z-isomers are known to be prepared by the hydrogenation of alkynes. - Keywords: Unsaturated ester; Unsaturated nitrile; F-Alkyl Chain; Dehydration; F-Enoyl sultam
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