Journal of Organometallic Chemistry p. 325 - 337 (1990)
Update date:2022-08-22
Topics:
Lindner, Ekkehard
Glaser, Erhard
Mayer, Hermann August
Wagner, Peter
The heterogenized (ether-phosphane)rhodium complexes O = Me3Si(CH2)3P(Ph)CH2CH2OCH3>.Oxidative addition of CH3I to 7e affords trans-(P<*>O)2Rh(CO)(CH3)(I)2 (9e).In the presence of CO methyl migration in 9e leads to trans-(P<*>O)2Rh(CO)(COCH3)(I)2 (10e).Reductive elimination of CH3C(O)I from 10e regenerates 7e, probably via the cationic intermediate
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