Journal of the Chemical Society. Chemical communications p. 825 - 826 (1986)
Update date:2022-08-11
Topics:
Bergeret, G.
Broyer, J. P.
David, M.
Gallezot, P.
Volta, J. C.
Hecquet, G.
The radical electron distribution obtained from X-ray patterns has been used to study the structure of a poorly-crystalline vanadium-phosphorus mixed oxide (VPO) catalyst after selective oxidation of n-butane; the effective catalyst consists of a mixture of a crystallized (VO)2P2O7 phase (V(4+)) and an amorphorus VPO phase (V(5+)) showing many corner-sharing VO6 octahedra.
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