Tetrahedron Letters p. 1697 - 1700 (1995)
Update date:2022-08-22
Topics:
Minisci, Francesco
Zhao, Lihua
Fontana, Francesca
Bravo, Anna
The oxidation of alkanes by dimethyldioxirane (DMD) in the presence of CBrCl3 provides strong evidence that free-radicals are involved in the reaction; enthalpic and polar effects and an "oxygen rebound" mechanism are suggested to explain the exceptional oxidation selectivity.
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