Kinetics and Mechanism of the Radical-Induced Deiodination of Aryl Iodides by Methoxide Ions

DOI: 10.1021/jo00035a032

Source and publish data:

Journal of Organic Chemistry p. 2710 - 2716 (1992)

Update date:2022-08-30

Topics:

Authors:

Tomaselli, Gaetano A.

Bunnett, Joseph F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00035a032

Kinetic study of the deiodination of m-chloroiodobenzene (to chlorobenzene and iodide ion), as effected by sodium or potassium methoxide in methanol, with initiation by thermolysis of azobisisobutyronitrile (AIBN), reveals kinetic orders 1.0 in aryl iodid

Full text of DOI:10.1021/jo00035a032

Products guided by the article

Product name:Chlorobenzene

Cas No:108-90-7

R&D Labs maybe for 108-90-7

Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Shandong Shouguang Songchuan Industrial Additives Co.,Ltd

Contact:+86-536-8566856

Address:Shouguang,Shandong,China
SHAANXI FUJIE PHARMACEUTICAL CO.,LTD

website:http://www.fujiepharm.com

Contact:+86-29-63650906

Address:Yuanqu Yi Road, Qinghe Food Industrial Park, Sanyuan County, Shaanxi Province, China
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA

Relevant to this article

Enantiopure Methyl- A nd Phenyllithium: Mixed (Carb-)Anionic Anisyl Fencholate-Aggregates

Doi:10.1021/acs.organomet.8b00724
(2019)
Characterizing the thermal degradation mechanism of two bisphosphoramidates by TGA, DSC, mass spectrometry and first-principle theoretical protocols

Doi:10.1016/j.molstruc.2020.128781
(2020)
A Boron Alkylidene–Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal

Doi:10.1002/anie.201705720
(2017)
Doi:10.1002/jhet.5570380208
(1955)
Doi:10.1007/BF00944436
()
The kinetics and mechanism of the homogeneous, unimolecular gas-phase elimination of 2-(4-substituted-phenoxy)tetrahydro-2H-pyranes

Doi:10.1002/poc.3778
(2018)

Article Doi