Journal of the Chemical Society. Chemical communications p. 1573 - 1574 (1995)
Update date:2022-08-16
Topics:
Bravo, Anna
Fontana, Francesca
Fronza, Giovanni
Mele, Andrea
Minisci, Francesco
The oxidation of alkanes by dimethyldioxirane is dramatically affected by the presence of molecular oxygen and radical inhibitors, supporting the hypothesis of a free-radical mechanism for these extraordinarily selective reactions; the factors affecting the free-radical selectivity are suggested.
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