Organosilane-mediated free radical cyclization reactions employing carbonyl traps

DOI: 10.1016/S0040-4039(98)01585-8

Source and publish data:

Tetrahedron Letters p. 7267 - 7270 (1998)

Update date:2022-08-11

Topics:

Authors:

Batey, Robert A.

MacKay, D. Bruce

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)01585-8

Free-radical cyclization of halocarbonyl compounds can be achieved using the organosilane reagents phenylsilane and tristrimethylsilylsilane. Both 6- exo-trig and 5-exo-trig cyclizations can be accomplished using aldehydes or ketones as radical traps.

Full text of DOI:10.1016/S0040-4039(98)01585-8

Products guided by the article

Product name:Cyclohexanol

Cas No:108-93-0

R&D Labs maybe for 108-93-0

EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China

Relevant to this article

Synthetic studies on d-biotin, part 8: An efficient chemoenzymatic approach to the asymmetric total synthesis of d-biotin via a polymer-supported PLE-mediated desymmetrization of meso-symmetic dicarboxylic esters

Doi:10.1002/adsc.200404311
(2005)
A New and Efficient Heterogeneous System for the Oxidative Cleavage of 1,2-Diols and the Oxidation of Hydroquinones

Doi:10.1055/s-1989-27155
(1989)
New non-protienogenic fluorescent amino acids: Benzoxazol-5-yl-alanine derivatives containing acetylene unit. Synthesis, spectral and photophysical properties

Doi:10.1016/j.jphotochem.2018.07.012
(2018)
Enantioselective catalytic borane reductions of achiral ketones: Synthesis and application of new rigid catalysts prepared from (R)-phenylglycine and (S)-phenylalanine

Doi:10.1080/00397919308018602
(1993)
Regiodivergent reduction of allylic esters with Samarium(II) iodide by tuning ester groups and proton sources

Doi:10.1016/S0040-4039(98)00042-2
(1998)
Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans-[Ru(NHC)₄H₂] through a Concerted Nucleophilic Ru?H Attack Pathway

Doi:10.1002/anie.201610820
(2017)

Article Doi