Organosilane-mediated free radical cyclization reactions employing carbonyl traps

DOI: 10.1016/S0040-4039(98)01585-8

Source and publish data:

Tetrahedron Letters p. 7267 - 7270 (1998)

Update date:2022-08-11

Topics:

Authors:

Batey, Robert A.

MacKay, D. Bruce

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Article abstract of DOI:10.1016/S0040-4039(98)01585-8

Free-radical cyclization of halocarbonyl compounds can be achieved using the organosilane reagents phenylsilane and tristrimethylsilylsilane. Both 6- exo-trig and 5-exo-trig cyclizations can be accomplished using aldehydes or ketones as radical traps.

Full text of DOI:10.1016/S0040-4039(98)01585-8

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