Journal of the Chemical Society. Perkin transactions II p. 1991 - 1995 (1990)
Update date:2022-08-24
Topics:
Kitano, Tomoyuki
Kuroda, Yasushi
Itoh, Akikazu
Li-Fen, Jian
Kunai, Atsutaka
Sasaki, Kazuo
Oxidation of benzene on silica-supported palladium catalysts has been studied under ambient conditions.Products are phenol and three quinones/quinols (benzoquinone, hydroquinone and catechol), with some minor products produced in negligible amount.Two types of catalyst, Pd alone and Cu-Pd composite catalysts, both being supported on silica gel, were found to behave in remarkably different ways.The palladium catalyst is effective only when hydrogen and oxygen are both present in the reaction sytem simultaneously and produces phenol almost exclusively
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