Oxidative Cleavage of Carbon-Silicon Bonds by Dioxygen: Catalysis by a Flavin-Dihydronicotinamide Redox System

DOI: 10.1039/c39880000795

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Journal of the Chemical Society. Chemical communications p. 795 - 797 (1988)

Update date:2022-08-11

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Authors:

Tamao, Kohei

Hayashi, Takashi

Ito, Yoshihiko

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Article abstract of DOI:10.1039/c39880000795

Carbon-silicon bonds in alkyloxy- or fluoro-silanes readily undergo cleavage by dioxygen (molecular oxygen), catalysed by tetra-acetylriboflavin (5-10 molpercent) in the presence of N-benzyl-1,4-dihydronicotinamide as reductant, together with fluoride ions as an essential additive.

Full text of DOI:10.1039/c39880000795

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