Efficient and Regioselective Cyanosilylation of Cyclohex-2-enone and Other Unsaturated Ketones over Solid Acid and Base Catalyst

DOI: 10.1039/c39910001035

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1035 - 1036 (1991)

Update date:2022-08-17

Topics:

Authors:

Higuchi, Katsumi

Onaka, Makoto

Izumi, Yusuke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910001035

Cyanotrimethylsilane reacts with α,β-unsaturated ketones to afford 1,4- and 1,2-adducts regioselectively in the presence of strongly acidic montmorillonite and strongly basic CaO or MgO, respectively.

Full text of DOI:10.1039/c39910001035

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-Butenenitrile, 2-methyl-4-phenyl-2-[(trimethylsilyl)oxy]-, (3E)-

Cas No:108583-48-8

R&D Labs maybe for 108583-48-8

Hangzhou utanpharma Co., Ltd

Contact:0571-86821378 ,86820258,56836287,56830923,

Address:Block D ,20F, Tianyuan Building,No.508, Wensan RD, 310013,Hangzhou Zhejiang China
LIAOYANG TENGYUAN FOOD ADDITIVE FACTORY

Contact:+86-419-5807666

Address:Haodianzi village,Hanling Town,Liaoyang county
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
Esuccess Material Limited

Contact:852-29282288

Address:HONGKONG
Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue

Relevant to this article

Nucleophilic fluorination of alkoxysilane with alkali metal hexafluorophosphate ¹ - part 1

Doi:10.1016/S0022-1139(97)00112-7
(1997)
Protonation and Anion Binding Properties of Aromatic Bis-Urea Derivatives—Comprehending the Proton Transfer

Doi:10.1002/chem.201805633
(2019)
Catalytic properties of Talaromyces thermophilus α-l- arabinofuranosidase and its synergistic action with immobilized endo-β-1,4-xylanase

Doi:10.1016/j.molcatb.2010.11.003
(2011)
Synthesis of highly substituted pyrrolidines through 1,3-dipolar cycloaddition reaction of N-metalated azomethine ylides with triarylideneacetylacetone as dipolarophile using titanocene dichloride

Doi:10.1080/00397910802621723
(2009)
Isoxazoles. 8. Preformulation studies of an isoxazolylnaphthoquinone derivative

Doi:10.1002/jps.2600830314
(1994)
Doi:10.1007/BF00799954
(1983)

Article Doi