Oxidation of prochiral sulfides with chiral dioxirane

Article abstract of DOI:10.1134/S1070428006010027

Dioxirane generated in situ by reaction of chiral 1,2:4,5-di-O- isopropylidene-D-erythro-hexo-2,4-diulo-2,6-pyranose with Oxone oxidizes prochiral sulfides to the corresponding sulfoxides with an enantiomeric excess of 2 to 25%. Pleiades Publishing, Inc., 2006.

Full text of DOI:10.1134/S1070428006010027

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ꢀꢆꢊꢂ 7Xꢄꢂ <ꢊꢄꢂ :DQJꢄꢂ =ꢊꢉ;ꢊꢄꢂ DQGꢂ 6KLꢄꢂ <ꢊꢄꢂ -ꢂꢀ $Pꢂꢀ &KHPꢂꢀ 6RFꢊꢄꢂ ꢁꢅꢊꢂ -SDWLHIIꢄꢂ 9ꢊ1ꢊꢄꢂ 3LQHVꢄꢂ +ꢊꢄꢂ DQGꢂ )ULHGPDQꢄꢂ %ꢊ&ꢊꢄꢂ -ꢂꢀ $Pꢂꢀ
ꢀꢑꢑꢃꢄꢂYROꢊꢂꢀꢀꢐꢄꢂSꢊꢂꢑꢐꢅꢃꢊꢂ &KHPꢂꢀ6RFꢊꢄꢂꢀꢑꢋꢐꢄꢂYROꢊꢂꢃꢅꢄꢂSꢊꢂꢁꢏꢋꢀꢊꢂ
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ꢀꢏꢊꢂ :HOEꢄꢂ.ꢊ6ꢊꢄꢂ7HWUDKHGURQꢀ/HWWꢊꢄꢂꢀꢑꢑꢆꢄꢂYROꢊꢂꢋꢈꢄꢂSꢊꢂꢋꢆꢈꢏꢊꢂ
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5866,$1ꢂꢂ-2851$/ꢂꢂ2)ꢂꢂ25*$1,&ꢂꢂ&+(0,675<ꢂꢂꢂ9ROꢊꢂꢂꢆꢁꢂꢂꢂ1Rꢊꢂꢂꢀꢂꢂꢂꢁꢅꢅꢃꢂ