Rearrangement of silanorbornadienes via photoinduced electron-transfer

DOI: 10.1016/0040-4039(95)01263-H

Source and publish data:

Tetrahedron Letters p. 6293 - 6296 (1995)

Update date:2022-08-29

Topics:

Authors:

Kako, Masahiro

Kakuma, Seiji

Hatakenaka, Kaname

Nakadaira, Yasuhiro

Yasui, Masanori

Iwasaki, Fujiko

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Article abstract of DOI:10.1016/0040-4039(95)01263-H

Irradiation of silanorbornadienes 1 using 9,10-dicyanoanthracene as a sensitizer afforded two isomers 2 and 3 accompanied with anthracene. In the presence of molecular oxygen, dioxide 5 was obtained as an additional product. These reactions are explained in terms of the initial electron donor-acceptor interaction followed by skeletal rearrangement.

Full text of DOI:10.1016/0040-4039(95)01263-H

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