On the Photochemical Behaviour of Ethyl Acetoacetate in Water

DOI: 10.1007/BF00799960

Source and publish data:

Monatshefte fur Chemie p. 1005 - 1008 (1983)

Update date:2022-08-11

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Authors:

Markov, Peter

Petkov, Ivan

Roumian, Christian

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Article abstract of DOI:10.1007/BF00799960

Irradiation of ethyl acetoacetate in water yielded acetic acid, ethyl acetate, acetonylacetone and diethyl succinate.The possible route of their formation is the recombination of the radicals resulting from the cleavage of the bonds between α-β and β-γ carbon atoms of the β-keto ester and /or their interaction with the solvent. - Keywords: Ethyl acetoacetate; Homolytic photocleavage; Solvent effect

Full text of DOI:10.1007/BF00799960

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