Monatshefte fur Chemie p. 1005 - 1008 (1983)
Update date:2022-08-11
Topics:
Markov, Peter
Petkov, Ivan
Roumian, Christian
Irradiation of ethyl acetoacetate in water yielded acetic acid, ethyl acetate, acetonylacetone and diethyl succinate.The possible route of their formation is the recombination of the radicals resulting from the cleavage of the bonds between α-β and β-γ carbon atoms of the β-keto ester and /or their interaction with the solvent. - Keywords: Ethyl acetoacetate; Homolytic photocleavage; Solvent effect
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(2020)Doi:10.1039/c39800000093
(1980)Doi:10.1107/S0108270195000485
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(1984)
