Journal of Fluorine Chemistry p. 289 - 296 (1985)
Update date:2022-08-30
Topics:
Paciorek, K. J. L.
Nakahara, J. H.
Kratzer, R. H.
Reaction of perfluoro-n-octanonitrile with diphenylphosphine gave two products: a primary adduct, C7F15C(=NH)P(C6H5)2, and the reduced adduct, C7F15CH(NH2)P(C5H5)2.Presence of water prevented the formation of the reduced compound; the latter was not produced by reduction of the primary adduct.Operative mechanisms are postulated; infrared and mass spectra are discussed.
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(2019)
