DIRECT PHOTOLYSIS AT 185 nm OF 1-ALKENES IN SOLUTION. MOLECULAR ELIMINATION OF TERMINAL HYDROGENS

DOI: 10.1246/cl.1984.1725

Source and publish data:

Chemistry Letters p. 1725 - 1728 (1984)

Update date:2022-08-16

Topics:

Authors:

Inoue, Yoshihisa

Mukai, Toshio

Hakushi, Tadao

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Article abstract of DOI:10.1246/cl.1984.1725

Direct irradiations at 185 nm of 1-octene and 2-methyl-1-pentene in pentane gave alkylidene carbenes through the molecular elimination of terminal hydrogens, as well as double-bond migration products via 1,3-shift of allylic hydrogen and radical-derived products.

Full text of DOI:10.1246/cl.1984.1725

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