5-C5Me5)2Ti>2(μ-OC)22 (cp = η5-C5H5): A Compound with Linear Coordination of Titanium to a Bridging Carbonyl and a d6-d6 2 Fragment

Article abstract of DOI:10.1039/C39850001666

Reaction of (η⁵-C5Me5)2Ti-neo-C5H11 with 2 (cp = η⁵-C5H5) yields the title compound (1); X-ray analysis of (1) shows a 4e (?, ?) Ti-O interaction, resulting in a novel linear co-ordination of titanium to a bridging carbonyl and a new geometry of a 2 fragment caused by a d⁶-d⁶ (Mo-Mo) electron count.

Full text of DOI:10.1039/C39850001666

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online