Journal of the Chemical Society. Chemical communications p. 89 - 90 (1985)
Update date:2022-08-11
Topics:
Bartok, Michaly
Molnar, Arpad
On γ-alumina gaseous (+/-)-2,2,3,4,5,5-hexamethyloxolane (1) is converted mainly into 2,3,4,5-tetramethylhexa-1,5-diene, while its meso-isomer (2) reacts at a higher rate than (1) to give 2,3,4,5-tetramethylhexa-2,4-diene with high selectivity; this is the first reported experimental observation of the stereochemistry of this dehydration reaction.
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Doi:10.1021/acs.orglett.8b01658
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(1976)
