Thiocarbonyl complexes of iron V. New thiocarbonyl complexes derived by substitution from Fe(CO)4CS

Article abstract of DOI:10.1016/0022-328X(88)80140-2

Reaction of Fe(CO)4CS (1) with PR3 (PR3 = PPh3, PPh2Me) in the presence of ONMe3 gives the substituted derivatives Fe(CO)3(CS)Pr3 (2) and Fe(CO)2(CS)(PR3)2 (3) in moderate yields.The compounds have been characterized by infrared, 13C, and 1H NMR spectrosc