Tetrahedron Letters p. 3103 - 3106 (1984)
Update date:2022-08-16
Topics:
Pellicciari, Roberto
Natalini, Benedetto
Cecchetti, Sergio
Santucci, Sergio
α-Diazomethyl ketones derived from carboxylic acids are photolyzed in the presence of imidazole to give the corresponding nor olefins or, in the case of aryl diazo ketones, the corresponding, stable imidazolides.The application of the method to a novel degradation of bile acid side chain is reported.
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