Catalytic osmylation of allenic compounds. Synthesis of α-hydroxyketo amino acid precursors

DOI: 10.1016/0040-4039(96)00571-0

Source and publish data:

Tetrahedron Letters p. 3335 - 3338 (1996)

Update date:2022-08-10

Topics:

Authors:

David, Katerine

Ariente, Cecile

Greiner, Alfred

Gore, Jacques

Cazes, Bernard

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Article abstract of DOI:10.1016/0040-4039(96)00571-0

Osmium tetroxyde-catalyzed dihydroxylation of allenic compounds in the presence of N-Methylmorpholine Oxide leads to α-ketols. Regioselectivity of this oxidation procedure with allenic α-amino acid precursors is greatly influenced by the nature and the remoteness of the protected amino acid group.

Full text of DOI:10.1016/0040-4039(96)00571-0

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