Tetrahedron Letters p. 3335 - 3338 (1996)
Update date:2022-08-10
Topics:
David, Katerine
Ariente, Cecile
Greiner, Alfred
Gore, Jacques
Cazes, Bernard
Osmium tetroxyde-catalyzed dihydroxylation of allenic compounds in the presence of N-Methylmorpholine Oxide leads to α-ketols. Regioselectivity of this oxidation procedure with allenic α-amino acid precursors is greatly influenced by the nature and the remoteness of the protected amino acid group.
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