NICKEL-CATALYZED STEREODIFFERENTIATING DISPLACEMENT REACTION BETWEEN PROCHIRAL 1-ALKENES AND OPTICALLY ACTIVE ORGANOALUMINIUM SOLVATES.

DOI: 10.1016/0040-4039(81)80021-4

Source and publish data:

Tetrahedron Letters p. 883 - 886 (1981)

Update date:2022-08-10

Topics:

Authors:

Giacomelli, Giampaolo

Bertero, Luigi

Lardicci, Luciano

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Article abstract of DOI:10.1016/0040-4039(81)80021-4

The displacement reaction between optically active AlBuⁱ3 solvates and vinylidene alkenes, in the presence of Ni(mesal)2, affords optically active trialkylalanes and hence, upon hydrolysis or oxidative procedure, alkanes or 1-alkanols.

Full text of DOI:10.1016/0040-4039(81)80021-4

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