Oxidation-reduction sequence for the synthesis of peracylated fluorodeoxy pentofuranosides

Article abstract of DOI:10.1080/15257779508012389

Oxidation of 1a with DMSO-acetic or trifluoroacetic anhydride led to the formation of a mixture of epimeric gem-diols 2 and 3 in the ratios of ?3:1 and ?7:1, respectively. Reduction of this mixture with NaBH₄ followed by benzoylation and chroma

Full text of DOI:10.1080/15257779508012389

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Nucleosides and Nucleotides
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Oxidation-Reduction Sequence for the
Synthesis of Peracylated Fluorodeoxy
Pentofuranosides
a
a
a
Igor A. Mikhailopulo , Nicolai E. Poopeiko , Grigorii G. Sivets
&
a
Natalia B. Khripach
a
Institute of Bioorganic Chemistry, Byelorussian Academy of
Sciences , 220141, Minsk, Zhodinskaya, 5/2, Byelorussia
Published online: 16 Feb 2007.
To cite this article: Igor A. Mikhailopulo , Nicolai E. Poopeiko , Grigorii G. Sivets & Natalia B. Khripach
1995) Oxidation-Reduction Sequence for the Synthesis of Peracylated Fluorodeoxy Pentofuranosides,
(
Nucleosides and Nucleotides, 14:3-5, 383-384
To link to this article: http://dx.doi.org/10.1080/15257779508012389
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