The nickel and palladium catalyzed stereoselective cross coupling of cyclopropyl nucleophiles with aryl halides

Article abstract of DOI:10.1080/00397919808005715

The reaction of 2-phenylcyclopropylzinc chloride with some substituted (het)aryl halides gave the corresponding coupling products with good yields and stereoselectivities under the influence of a catalytic amount of Pd(PPh₃)₄. Other Ni- and Pd-catalysts were less efficient. Alkyl-substituted cyclopropyl nucleophiles gave lower yields.

Full text of DOI:10.1080/00397919808005715

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Synthetic Communications:
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The Nickel and Palladium
Catalysed Stereoselective
Cross Coupling of
Cyclopropyl Nucleophiles
with Aryl Halides
R.-J. de Lang a & L. Brandsma a
a Department of Preparative Organic Chemistry,
Utrecht University, Padualaan 8, 3584, CH,
Utrecht, The Netherlands
Available online: 21 Aug 2006
To cite this article: R.-J. de Lang & L. Brandsma (1998): The Nickel and
Palladium Catalysed Stereoselective Cross Coupling of Cyclopropyl Nucleophiles
with Aryl Halides, Synthetic Communications: An International Journal for Rapid
Communication of Synthetic Organic Chemistry, 28:2, 225-232
To link to this article: http://dx.doi.org/10.1080/00397919808005715
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