ULTRASONICALLY IMPROVED REDUCTIVE PROPERTIES OF AN AQUEOUS Zn-NiCl2 SYSTEM - 2. REGIOSELECTIVITY IN THE REDUCTION OF (-)-CARVONE

DOI: 10.1016/S0040-4039(00)96121-5

Source and publish data:

Tetrahedron Letters p. 2351 - 2352 (1987)

Update date:2022-08-11

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Authors:

Petrier, Christian

Luche, Jean-Louis

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Article abstract of DOI:10.1016/S0040-4039(00)96121-5

While the previously described reductive system Zn-NiCl2 leads to the non-selective hydrogenation of the two olefinic bonds of (-)-carvone 1, the two selective hydrogenation products (+)-dihydrocarvone 2 and carvotaneacetone 3 are obtained in good yield with the same reagent under modified experimental conditions.

Full text of DOI:10.1016/S0040-4039(00)96121-5

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