Copper(I) and Copper(II) mediated Two-electron Oxidations of Benzylic Alcohols and Diaryl Acetic Acids by Trimethylamine N-Oxide

DOI: 10.1039/c39900000565

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Journal of the Chemical Society. Chemical communications p. 565 - 566 (1990)

Update date:2022-08-10

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Authors:

Capdevielle, Patrice

Sparfel, Daniel

Baranne-Lafont, Joele

Cuong, Nguyen Kim

Maumy, Michel

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Article abstract of DOI:10.1039/c39900000565

A novel ligand oxidation of Cu^I and Cu^II benzylic alcoholates and diaryl acetic carboxylates to carbonyl compounds by trimethylamine N-oxide gives support to the existence of cupryl (-Cu^III=O) intermediates, previously postulated in the reaction of Cu^I derivatives with dioxygen.

Full text of DOI:10.1039/c39900000565

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