Journal of the Chemical Society. Chemical communications p. 565 - 566 (1990)
Update date:2022-08-10
Topics:
Capdevielle, Patrice
Sparfel, Daniel
Baranne-Lafont, Joele
Cuong, Nguyen Kim
Maumy, Michel
A novel ligand oxidation of CuI and CuII benzylic alcoholates and diaryl acetic carboxylates to carbonyl compounds by trimethylamine N-oxide gives support to the existence of cupryl (-CuIII=O) intermediates, previously postulated in the reaction of CuI derivatives with dioxygen.
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