Tetrahedron Letters p. 3057 - 3060 (1999)
Update date:2022-08-16
Topics:
Bumagin, Nikolay A.
Korolev, Dmitriy N.
The cross-coupling reaction of sodium tetra-arylborates with acyl chlorides to give high yields of unsymmetric ketones has been carried out at 20°C in the presence of Pd(OAc)2 and Na2CO3 in dry or aqueous acetone. Under aqueous conditions arylboronic acids react smoothly with benzoyl chloride resulting in substituted benzophenones.
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