A Novel Method for the Conversion of Halide Anion to the Positive Halogen by Nitrobenzenesulfonyl Peroxide. Application to Oxyhalogenation of Olefin

DOI: 10.1246/bcsj.63.3704

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3704 - 3706 (1990)

Update date:2022-08-30

Topics:

Authors:

Yoshida, Masato

Mochizuki, Hideki

Suzuki, Takashi

Kamigata, Nobumasa

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Article abstract of DOI:10.1246/bcsj.63.3704

Bromide and chloride anions could be readily oxidized into positive halogens by treating with p-nitrobenzenesulfonyl peroxide.The positive halogens, thus formed, reacted with olefins to give epihalonium ions, which were trapped by oxygen nucleophiles inter- or intramolecularly to afford oxyhalogenated compounds.

Full text of DOI:10.1246/bcsj.63.3704

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