A FACILE SYNTHESIS OF 1,3-CYCLOALKADIONES

DOI: 10.1246/cl.1981.551

Source and publish data:

Chemistry Letters p. 551 - 554 (1981)

Update date:2022-08-16

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Authors:

Nishiguchi, Ikuzo

Hirashima, Tsuneaki

Shono, Tatsuya

Sasaki, Manji

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Article abstract of DOI:10.1246/cl.1981.551

1,3-Cycloalkadiones were prepared by the reaction of 1,2-bis(trimethylsiloxy)cycloalkenes with chloromethyl methyl ether followed by treatment of the resulting 2-hydroxy-2-methoxymethyl cycloalkanones with potassium hydrogen sulfate.The first step of the reactions was effectively catalyzed by active zinc reagents prepared from zinc-copper and alkyl iodides.

Full text of DOI:10.1246/cl.1981.551

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