Synthesis and Crystal Structure of 4-η2-CCt-Bu)(CO)7(dppe)> (dppe=Ph2PCH2CH2PPh2), a Butterfly Cluster containing an unusually Bonded Alkynyl Ligand: A Model for an Intermediate Molecular Geometry in a Cluster-Ligand Rearrangement

DOI: 10.1039/c39910000163

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 163 - 165 (1991)

Update date:2022-09-26

Topics:

Authors:

Farrugia, Louis J.

MacDonald, Neil

Peacock, Robert D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000163

Reaction of 4-η²-CCt-Bu)(CO)9(L₂) 1a (L₂=dppe) with Ph2PCCPPh2 affords the butterfly cluster 4-η²-CCt-Bu)(CO)7(dppe)> 3; the metal skeleton and μ₄-η² alkynyl coordination mode in 3 represent a likely model for a transition geometry in the interconversion of 1 and its vinylidene tautomer 4-η²-C=C(H)t-Bu>(CO)9(L₂)> 2.

Full text of DOI:10.1039/c39910000163

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe)

Cas No:119567-03-2

R&D Labs maybe for 119567-03-2

KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Anhui Redstar Pharmaceutical Corp., Ltd

Contact:+86-563-5120837

Address:Jingxian Industrial Development Zone, Anhui , China
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.

Relevant to this article

Regioselectivity of the palladium-mediated intramolecular coupling reaction of highly oxygenated phenyl benzoate derivatives and application to the synthesis of altertenuol

Doi:10.3987/COM-13-12859
(2014)
Discovery and optimization of potent and selective functional antagonists of the human adenosine A_2B receptor

Doi:10.1016/j.bmcl.2009.08.040
(2009)
Cesium Salt-Catalyzed Addition of Diphenyl Dichalcogenides to Alkynes: Selective Synthesis of Bis- and Mono(phenylchalcogeno)alkenes

Doi:10.1246/bcsj.82.1170
(2009)
A Double plug-socket system capable of molecular keypad locks through controllable photooxidation

Doi:10.1002/chem.200901206
(2009)
Impact of chelation on anticancer activities of organometallic ruthenium(II) complexes containing 2,5-di(1: H -pyrazol-1-yl)-1,4-benzoquinone: Synthesis, structure, DNA/protein binding, antioxidant activity and cytotoxicity

Doi:10.1039/c6ra05867a
(2016)
Catalytic defluorination of perfluorinated aromatics under oxidative conditions using N-bridged diiron phthalocyanine

Doi:10.1021/ja505437h
(2014)

Article Doi