A Convergent Total Synthesis of (+)-Phyllanthocin

DOI: 10.1021/jo00392a046

Source and publish data:

Journal of Organic Chemistry p. 3706 - 3708 (1987)

Update date:2022-09-26

Topics: Total synthesis Work-Up Convergent Synthesis Reaction flask

Authors:

Martin, Stephen F.

Dappen, Michael S.

Dupre, Brian

Murphy, Christopher J.

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Article abstract of DOI:10.1021/jo00392a046

A highly convergent, enantioselective total synthesis of (+)-phyllanthocin (1), the aglycone of the antineoplastic agent phyllanthoside (2), has been achieved by employing a novel strategy that features a stereo- and regioselective dipolar cycloaddition o

Full text of DOI:10.1021/jo00392a046

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