ADDITONS OF ANIONIC NUCLEOPHILES TO CARBONYL COMPOUNDS : CATION AND ELECTROPHILE NATURE INFLUENCE ON IONIC ASSOCIATION VS CARBONYL COMPLEXATION CONTROL

DOI: 10.1016/S0040-4039(01)90411-3

Source and publish data:

Tetrahedron Letters p. 1685 - 1688 (1981)

Update date:2022-08-30

Topics:

Authors:

Loupy, A.

Roux-Schmitt, M. C.

Seyden-Penne, J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)90411-3

The raction of benzaldehyde with LiCH2CN in THF is controlled by carbonyl complexation while with KCH2CN the reaction is controlled by ionic association.In the reaction of m.Cl.C6H4CHCN(1-)/Li(1+) with substituted benzaldehydes, carbonyl complexation prevails with p.CH3OC6H4CHO while ionic association dominates with PhCHO and p.CNC6H4CHO.

Full text of DOI:10.1016/S0040-4039(01)90411-3

Products guided by the article

Product name:3-hydroxy-3-phenylpropanenitrile

Cas No:121617-17-2

R&D Labs maybe for 121617-17-2

Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park
Jinan Xinke Pharmaceutical Science and Technology Co., Ltd.

Contact:+86 13256107535

Address:No. 592 the first gangxing road
SuZhou Hua-Emy Chemical Import and Export Co., LTD.

Contact:+86-512-88804994; +86-512-88804550;

Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China

Relevant to this article

BSA nanoparticles as controlled release carriers for isophethalaldoxime palladacycle complex; Synthesis, characterization,: In vitro evaluation, cytotoxicity and release kinetics analysis

Doi:10.1039/c9nj05847h
(2020)
Stereocomplementary synthesis of a natural product-derived compound collection on a solid phase

Doi:10.1039/b607816h
(2006)
Doi:10.1016/S0022-328X(00)85398-X
(1969)
Efficient method for cleavage of aziridines with aromatic amines

Doi:10.1021/jo981869r
(1999)
Half-sandwich Ru (II) complexes containing (N, O) Schiff base ligands: Catalysts for base-free transfer hydrogenation of ketones

Doi:10.1002/aoc.5111
(2019)
Influence of the synthesis method parameters used to prepare nickel-based catalysts on the catalytic performance for the glycerol steam reforming reaction

Doi:10.1016/S1872-2067(16)62518-4
(2016)

Article Doi