Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics p. 1161 - 1164 (1983)
Update date:2022-08-11
Topics:
Baro
Dudek
Luther
Troe
Solid 1,3-diphenyltriazene (DPT) has been photolyzed at 290 nm and 360 nm. The distribution of the photoproducts showed that recombination of the radicals produced after photochemical excitation was governed by a 'cage effect' favoring a minimum of motion of the recombining radicals. In many details the results differ from observations on the photochemistry of DPT in liquid solutions. The photolysis of DPT in polymethylmethacrylate films, however, resembles the photochemistry of DPT in liquid solutions.
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