INFLUENCE OF THE ANION ON COPPER ELECTROCRYSTALLIZATION.

Article abstract of DOI:10.1149/1.2127596

Structural studies of copper electrodepositions from pyrophosphate, chloride, cyanide, and citrate solutions were carried out on highly polished (001) copper surfaces at a wide range of current densities under galvanostatic conditions. The study was performed by means of x-ray diffraction. The deposition morphology was observed with a scanning electron microscope. Correlation among internal structure, surface morphology, solution composition, and plating conditions were examined. The results were compared with previous studies from sulfate solutions. Expitaxial growth was observed in the early stage of deposition. The effect of the anion on the change from single crystalline to polycrystalline growth at further stage is analyzed.

Full text of DOI:10.1149/1.2127596

Downloaded on 2013-11-10 to IP 128.143.23.241 address. Redistribution subject to ECS license or copyright; see ecsdl.org/site/terms_use

Downloaded on 2013-11-10 to IP 128.143.23.241 address. Redistribution subject to ECS license or copyright; see ecsdl.org/site/terms_use

Downloaded on 2013-11-10 to IP 128.143.23.241 address. Redistribution subject to ECS license or copyright; see ecsdl.org/site/terms_use

Downloaded on 2013-11-10 to IP 128.143.23.241 address. Redistribution subject to ECS license or copyright; see ecsdl.org/site/terms_use

Downloaded on 2013-11-10 to IP 128.143.23.241 address. Redistribution subject to ECS license or copyright; see ecsdl.org/site/terms_use

Downloaded on 2013-11-10 to IP 128.143.23.241 address. Redistribution subject to ECS license or copyright; see ecsdl.org/site/terms_use

Downloaded on 2013-11-10 to IP 128.143.23.241 address. Redistribution subject to ECS license or copyright; see ecsdl.org/site/terms_use