Journal of Organic Chemistry p. 2755 - 2758 (1991)
Update date:2022-08-30
Topics:
Lovett, Eva G.
Stable quaternary ammonium alkoxides, a new type of organic strong base, were obtained from unhindered tertiary alkanolamines and glycidol.At elevated temperatures, the 2-hydroxyethyl derivatives underwent intramolecular rearrangements and deoxyalkylation to form tertiary amine terminated 1,4-poly(3-hydroxyoxetanes).Demethylation was also observed.The 3-hydroxypropyl derivative underwent disproportionation and Hofmann elimination in addition.
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