Bulletin of the Chemical Society of Japan p. 3408 - 3412 (1984)
Update date:2022-08-16
Topics:
Yamamoto, Shunzo
Matsuda, Shuzo
Ozaki, Chihiro
Takahoso, Hiroshi
Nishimura, Norio
The mercury- and cadmium-photosensitized rections of γ-butyrolactone have been compared.The products obtained in the two photosensitizations were quite different.The gaseous products from the mercury-photosensitized reaction were carbon dioxide, cyclopropane, and propylene, while the products obtained in the cadmium-photosensitized reaction were carbon monoxide and ethylene.This difference suggests that the decomposition of γ-butyrolactone takes place through different intermediates in the two reactions.Possible mechanisms are discussed.
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