Chemistry Letters p. 541 - 542 (1995)
Update date:2022-08-17
Topics:
Ueda, Wataru
Suzuki, Yasuhiro
Propane was catalytically oxidized to acrylic acid and acetic acid with molecular oxygen at 360 deg C over heteropolymolybdophosphoric acids which were treated with pyridine in the catalyst preparation.Under presently optimized reaction conditions 24percent selectivity to acrylic acid and 15percent to acetic acid were achieved at 12percent conversion of propane.A reduced state of the catalyst generated by heat-treatment of the pyridine-treated heteropoly acid is important for the selectivities.
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