Journal of molecular catalysis p. 163 - 169 (1991)
Update date:2022-08-24
Topics:
Kiiski
Venalainen
Pakkanen
Krause
Heterogeneous catalysis of he water-gas shift reaction by Ru3(CO)12 with 2,2′-bipyridine on various inorganic supports was studied in a flow reactor (T = 100-150°C, P(CO) = 7.0 bar). Silica gel, magnesium silicate and Y, X and mordenite zeolites in Na form were found suitable support materials for the catalyst. The highest activity, 8170 mol H2/mol Ru3(CO)12 per 24 h, was obtained with magnesium silicate carrier at 150°C.
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