Journal of Solid State Chemistry p. 257 - 271 (1988)
Update date:2022-08-17
Topics:
Sourisseau, C.
Gwet, S. P.
Gard, P.
Mathey, Y.
The Li//3MS//3 powder samples (M**I**I**I equals Ti,Zr,Hf), chemically prepared under mild conditions, have been studied by X-ray diffraction, infrared and Raman vibrational spectroscopies, UV-visible absorption, and electron paramagnetic resonance (EPR) technics. From X-ray data we confirm the topochemical mechanism of three lithium insertions into the 2D-MS//3 host lattices already proposed by R. R. Chianelli and M. B. Dines. From infrared and Raman results new structural information is obtained: on the one hand, the cleavage of (S//2)**2** minus pairs induces a new arrangement of the basic structure and on the other hand, Li-S interactions are by far predominant within strongly distorted two LiS//4 and one LiS// 6 groups; moreover M-S interactions are markedly weakened.
Contact:86-10-62664360
Address:Building 10,No.18 AnNingZhuang East Road, GuangHua Pioneer Park,HaiDian District, BeiJing China
website:http://www.cartoonchem.com/
Contact:+86-25-58074918
Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Engineering Research Center of Pesticide, Heilongjiang Province
Contact:+86-451-86609001
Address:No.74 of Xuefu Road, Nangang District,
Contact:+86-511-88790000
Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Yangzhou Siyu Chemical Co.,Ltd.
Contact:+86-514-87325867 13358126196
Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Doi:10.1007/s11243-020-00407-7
(2020)Doi:10.1016/j.ejmech.2015.10.053
(2016)Doi:10.1016/S0040-4039(00)97549-X
(1982)Doi:10.1016/j.molcata.2016.11.007
(2017)Doi:10.1021/jo00097a012
(1994)Doi:10.1002/ejoc.202000094
(2020)
