A new homogeneous platinum containing catalyst for the hydrolysis of nitriles

DOI: 10.1016/0040-4039(95)01785-G

Source and publish data:

Tetrahedron Letters p. 8657 - 8660 (1995)

Update date:2022-08-24

Topics:

Authors:

Ghaffar, Talk

Parkinsa, Adrian W.

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Article abstract of DOI:10.1016/0040-4039(95)01785-G

[(Me₂PO···H···OPMe₂)PtH(PMe₂OH) is an extremely active homogeneous catalyst for the hydration of nitriles to amides: a mechanism involving intramolecular attack by a phosphine oxide on a nitrile within the co-ordination sphere of the platinum atom is suggested.

Full text of DOI:10.1016/0040-4039(95)01785-G

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