Enantioselective Olefin Epoxidation with Chiral Manganese/1,4,7-Triazacyclononane Complexes 1

DOI: 10.1055/s-1997-3244

Source and publish data:

Synlett p. 687 - 688 (1997)

Update date:2022-08-18

Topics:

Authors:

Bolm, Carsten

Kadereit, Dieter

Valacchi, Michela

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Article abstract of DOI:10.1055/s-1997-3244

Complexes prepared in situ from chiral N-substituted 1,4,7-triazacyclononanes and manganese(II) acetate catalyze the asymmetric oxidation of unfunctionalized olefins with hydrogen peroxide to give optically active epoxides under mild reaction conditions.

Full text of DOI:10.1055/s-1997-3244

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