Radical cyclization of (bromomethyl)dimethylsilyl propargyl ethers regioselective intramolecular cyclization of vinyl radicals

DOI: 10.1016/S0040-4039(00)97644-5

Source and publish data:

Tetrahedron Letters p. 4445 - 4448 (1990)

Update date:2022-08-16

Topics:

Authors:

Journet Journet

Magnol Magnol

Agnel Agnel

Malacria

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97644-5

Vinyl radical intermediates generated from radical cyclization of (bromomethyl)dimethylsilyl propargyl ethers have been trapped intramolecularly by a double bond leading to functionalized carbocycles with high yield and high regioselectivity.

Full text of DOI:10.1016/S0040-4039(00)97644-5

Products guided by the article

Product name:Silane, (bromomethyl)[(1,1-dimethyl-7-octen-2-ynyl)oxy]dimethyl-

Cas No:130747-92-1

R&D Labs maybe for 130747-92-1

Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Shandong united-rising pharmaceutical cooperation.,ltd.

Contact:008653187965009

Address:171No., Jing5 Road, Shizhong District, Jinan, China
Shanghai Sharing technologies Co., Ltd.

Contact:86-021-66787223

Address:No11, Lane 225, Jinxiang Road,Pudong district

Relevant to this article

Palladium(II)-Catalyzed Diastereoselective Acetalization of Hydroxyalkenes

Doi:10.1246/cl.1990.1387
(1990)
DBU-promoted nucleophilic activation of carbonic acid diesters

Doi:10.1002/ejoc.201001725
(2011)
Si-OSO₃H catalyzed one-pot three-component synthesis of 1,3-oxazines

Doi:10.1007/s13738-014-0423-9
(2014)
Novel chalcone derivatives as potent Nrf2 activators in mice and human lung epithelial cells

Doi:10.1021/jm2002348
(2011)
Solution processable indoloquinoxaline derivatives containing bulky polyaromatic hydrocarbons: Synthesis, optical spectra, and electroluminescence

Doi:10.1021/jo2004764
(2011)
REAGENT CONTROL IN THE ALDOL ADDITION OF CHIRAL BORON ENOLATES BASED ON THE 2,5-DIPHENYLBOROLANE LIGAND SYSTEM

Doi:10.1016/S0040-4039(00)97489-6
(1990)

Article Doi