Manganese(III)-based oxidative freeradical reaction of α-allyl-β-keto ester with molecular oxygen

DOI: 10.1016/S0040-4039(00)61371-0

Source and publish data:

Tetrahedron Letters p. 8509 - 8512 (1993)

Update date:2022-08-29

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Authors:

Ohshima, Takashi

Sodeoka, Mikiko

Shibasaki, Masakatsu

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Article abstract of DOI:10.1016/S0040-4039(00)61371-0

Oxidative reactions of α-allyl-β-keto esters 5 with Mn(OAc)₃·2H₂O give the δ-hydroxy-β-,γ-unsaturated-α-keto esters 6 in good yields. The mechanism of this reaction is discussed.

Full text of DOI:10.1016/S0040-4039(00)61371-0

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