Tetrahedron Letters p. 7843 - 7846 (1997)
Update date:2022-08-11
Topics:
Bergbreiter, David E.
Liu, Yun-Shan
The synthesis of a water-soluble polymer-bound Pd(0)-phosphine catalyst is described. This soluble polymeric catalyst is soluble in aqueous or mixed aqueous/organic media and has high activity in nucleophilic allylic substitution and in sp-sp2 coupling reactions of aryl iodides with terminal alkynes. The catalyst can be recycled efficiently by solvent or thermal precipitation methods.
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