Journal of Organometallic Chemistry p. 269 - 274 (1987)
Update date:2022-08-31
Topics:
Massonneau, Viviane
Maux, Paul Le
Simonneaux, Gerard
α,β-Unsaturated ketones have been hydrogenated in the presence of HRuCl(TBPC)2 (TBPC) = (-)-trans-1,2-bis(diphenylphosphinomethyl)cyclobutane) to give ketones with a maximum optical purity of 62percent.Factors affecting the stereoselectivity of the catalytic reaction are discussed.
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