Tetrahedron Letters p. 79 - 82 (1980)
Update date:2022-08-11
Topics:
Hayashi, Tamio
Fukushima, Motoo
Konishi, Mitsuo
Kumada, Makoto
Chiral β-dimethylaminoalkylphosphines were prepared starting with amino acids, (S)-alanine, (S)-phenylalanine, (R)-phenylglycine, (S)-valine, and (R)-tert-leucine. The chiral phosphines were found to be highly efficient ligands for a nickel catalyzed asymmetric Grignard cross-coupling reaction (38~94% optical yield).
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