Cluster versus non-cluster catalysis in olefin thermal isomerization and hydrosilylation in the presence of Ru(CO)12

DOI: 10.1016/0022-328X(93)83186-Y

Source and publish data:

Journal of Organometallic Chemistry p. 167 - 173 (1993)

Update date:2022-08-17

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Authors:

Hilal, Hikmat S.

Khalaf, Shukri

Jondi, Waheed

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Article abstract of DOI:10.1016/0022-328X(93)83186-Y

The ruthenium cluster Ru3(CO)12 (1) has been evaluated as a catalyst precursor for the thermal reactions of 1-octene with (EtO)3SiH in a mixture of dioxane and benzene at temperatures of 50-75 deg C.At 70 deg C or higher, olefin isomerization and hydrosil

Full text of DOI:10.1016/0022-328X(93)83186-Y

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