Tetrahedron p. 9495 - 9504 (1994)
Update date:2022-08-29
Topics:
Ramachandran
Eswaramoorthy
Sureshkumar
The kinetics of oxidation of amino acids (AA) by peroxomonosulphate in aqueous alkaline medium at 35°C is studied. Based on the experimental results, a reaction scheme is proposed in which the electrophilic attack of HSO5- occurs at the amino nitrogen. The break down of the intermediate is influenced by the nature of the substituent at the amino carbon atom. The formation of imine/imino acid is supported by the absorption spectra of the intermediate.
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