Catalytic Asymmetric Nitroaldol Reactions. A New Practical Method for the Preparation of the Optically Active Lanthanum Complex

DOI: 10.1016/0040-4039(93)89030-T

Source and publish data:

Tetrahedron Letters p. 851 - 854 (1993)

Update date:2022-08-11

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Authors:

Sasai, Hiroaki

Suzuki, Takeyuki

Itoh, Noriie

Shibasaki, Masakatsu

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Article abstract of DOI:10.1016/0040-4039(93)89030-T

The optically active La complex, which catalyzes asymmetric nitroaldol reactions, was found to be readily prepared from LaCl3*7H2O.The presence of water, LiCl or LiBr and an alkali metal hydroxide was essential for the formation of the effective lanthanum

Full text of DOI:10.1016/0040-4039(93)89030-T

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