Bis(trimethylsilyl) Peroxide for the Baeyer-Villiger Type Oxidation

DOI: 10.1021/jo00344a035

Source and publish data:

Journal of Organic Chemistry p. 902 - 904 (1982)

Update date:2022-08-30

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Authors:

Suzuki, M.

Takada, H.

Noyori, R.

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Article abstract of DOI:10.1021/jo00344a035

A Baeyer-Villiger type oxidation of ketonic substrates is achievable under aprotic conditions by use of bis(trimethylsilyl) peroxide and a catalytic amount of trimethylsilyl trifluoromethanesulfonate.The oxidation occurs specifically at carbonyl function and carbon-carbon double bonds are not affected.

Full text of DOI:10.1021/jo00344a035

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