Bis(trimethylsilyl) Peroxide for the Baeyer-Villiger Type Oxidation

DOI: 10.1021/jo00344a035

Source and publish data:

Journal of Organic Chemistry p. 902 - 904 (1982)

Update date:2022-08-30

Topics:

Authors:

Suzuki, M.

Takada, H.

Noyori, R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00344a035

A Baeyer-Villiger type oxidation of ketonic substrates is achievable under aprotic conditions by use of bis(trimethylsilyl) peroxide and a catalytic amount of trimethylsilyl trifluoromethanesulfonate.The oxidation occurs specifically at carbonyl function and carbon-carbon double bonds are not affected.

Full text of DOI:10.1021/jo00344a035

Products guided by the article

Product name:Hexyl acetate

Cas No:142-92-7

R&D Labs maybe for 142-92-7

Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Jurong Huaheng Natural Biological Products Factory

website:http://www.risebiochem.com

Contact:+86-13921007726

Address:Chuncheng town,Jurong city,Jiangsu province,China
Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
NEW LUNA PHARM CO.,LTD

Contact:Type:+86-0311-85637430

Address:#23.NANSAN ROAD,FENGTAI AREA,BEIJING CITY.
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china

Relevant to this article

Design, synthesis, and biological evaluation of novel 1,3,4-thiadiazole derivatives as potential antitumor agents against chronic myelogenous leukemia: Striking effect of nitrothiazole moiety

Doi:10.3390/molecules23010059
(2018)
Synthesis of copper containing polyaniline composites through interfacial polymerisation: An effective catalyst for Click reaction at room temperature

Doi:10.1016/j.molstruc.2021.130019
(2021)
Effect of Temperature and Solvent on the 1,3-Dipolar Cycloaddition of Diazodiphenylmethane with Several Dipolarophiles

Doi:10.1246/bcsj.55.3325
(1982)
Endo-Endo Mode Intramolecular Reductive Cyclization of Cyclic 1,2-Bis(silylethynyl)benzenes

Doi:10.1246/cl.2003.1104
(2003)
Contribution of Energy Transfer from the Singlet State to the Sensitization of Eu³⁺and Tb³⁺Luminescence by Sulfonylamidophosphates

Doi:10.1002/chem.201603767
(2017)
Synthesis of Indenopyridine Derivatives via MgI₂-Promoted [2+4] Cycloaddition Reaction of In-situ Generated 2-Styrylmalonate from Donor-Acceptor Cyclopropanes and Chalconimines

Doi:10.1002/adsc.201800598
(2018)

Article Doi