Bis(trimethylsilyl) Peroxide for the Baeyer-Villiger Type Oxidation

DOI: 10.1021/jo00344a035

Source and publish data:

Journal of Organic Chemistry p. 902 - 904 (1982)

Update date:2022-08-30

Topics:

Authors:

Suzuki, M.

Takada, H.

Noyori, R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00344a035

A Baeyer-Villiger type oxidation of ketonic substrates is achievable under aprotic conditions by use of bis(trimethylsilyl) peroxide and a catalytic amount of trimethylsilyl trifluoromethanesulfonate.The oxidation occurs specifically at carbonyl function and carbon-carbon double bonds are not affected.

Full text of DOI:10.1021/jo00344a035

Products guided by the article

Product name:Hexyl acetate

Cas No:142-92-7

R&D Labs maybe for 142-92-7

JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
SHENYANG COMEBOARD TECHNOLOGY CO., LTD

Contact:+86-24-25724626

Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Shanxi Tongji Pharmaceuticals Co., Ltd.

Contact:+86-359-3024784

Address:Xikuang South Road, Ruicheng County , Shanxi
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA

Relevant to this article

Design, synthesis, and biological evaluation of novel 1,3,4-thiadiazole derivatives as potential antitumor agents against chronic myelogenous leukemia: Striking effect of nitrothiazole moiety

Doi:10.3390/molecules23010059
(2018)
Synthesis of copper containing polyaniline composites through interfacial polymerisation: An effective catalyst for Click reaction at room temperature

Doi:10.1016/j.molstruc.2021.130019
(2021)
Effect of Temperature and Solvent on the 1,3-Dipolar Cycloaddition of Diazodiphenylmethane with Several Dipolarophiles

Doi:10.1246/bcsj.55.3325
(1982)
Endo-Endo Mode Intramolecular Reductive Cyclization of Cyclic 1,2-Bis(silylethynyl)benzenes

Doi:10.1246/cl.2003.1104
(2003)
Contribution of Energy Transfer from the Singlet State to the Sensitization of Eu³⁺and Tb³⁺Luminescence by Sulfonylamidophosphates

Doi:10.1002/chem.201603767
(2017)
Synthesis of Indenopyridine Derivatives via MgI₂-Promoted [2+4] Cycloaddition Reaction of In-situ Generated 2-Styrylmalonate from Donor-Acceptor Cyclopropanes and Chalconimines

Doi:10.1002/adsc.201800598
(2018)

Article Doi