Surprising Reactivity of Very Crowded Phosphinic Derivatives

DOI: 10.1039/c39810001197

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1197 - 1198 (1981)

Update date:2022-08-10

Topics:

Authors:

Baceiredo, Antoine

Bertrand, Guy

Mazerolles, Pierre

Majoral, Jean-Pierre

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Article abstract of DOI:10.1039/c39810001197

An example of intramolecular cyclisation of a crowded phosphinic chloride via loss of hydrogen chloride and formation of a phosphorus-carbon bond is described; unexpected cleavage of an acyclic phosphorus-carbon bond is also reported.

Full text of DOI:10.1039/c39810001197

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